
3) Simulations related to figure 4A, 4B and 4C.

Simulated and experimental voltammograms related to Figure 4, includin simuglations of an E-step with k0 ranging from 10-8 to 10-3 cm s-1 compared with the anodic waves of anC-Spy and anC-Rpy at 0.020 V·s-1 (A);best fits of simulated VO2+ (dotted lines) and experimental (solid lines) anodic waves for VO2+ oxidation (B); and SSE figures of merit as a function of the k0 values used in the simulations for all four surfaces investigated (C).

This dataset corresponds to the voltammetric simulations and experimental fits used to evaluate the electron-transfer kinetics, where the minima in the SSE curves indicate the best-fit values of k0.

